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Opis

Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Br

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Kategoria Książki po angielsku Mathematics & science Chemistry Organic chemistry

• Pełny tytuł: Organic Reactions V73 Carbonyl Allylboration
• Autor: Dennis G. Hall, Roger Adams, Leo A. Paquette
• Język: Angielski
• Oprawa: Miękka
• Liczba stron: 596
• EAN: 9781118344453
• ISBN: 1118344456
• ID: 01401885
• Wydawca: John Wiley & Sons Inc
• Waga: 878 g
• Wymiary: 228 × 157 × 31 mm
• Data wydania: 01. December 2012

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