Code: 05182812
Rotation about the Carbon-Carbon single bond is generally§regarded to be unrestricted. About 50 years ago, rotational§isomers were found to exhibit optical activity: substituted§biphenyl derivatives. However, the author has invest ... more
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Rotation about the Carbon-Carbon single bond is generally§regarded to be unrestricted. About 50 years ago, rotational§isomers were found to exhibit optical activity: substituted§biphenyl derivatives. However, the author has investigated§other classes of compounds that have stable rotational§isomers at room temperature. These compounds can serve as§models for studying very weak intermolecular interactions,§that are difficult to observe. Even diastereotopic groups§show different chemical reactivity.§From the contents: The "Free Rotation Concept" - Rotamer§Populations - Barriers to Rotation - Reactivity of§Rotational Isomers.
Book category Books in English Mathematics & science Chemistry Organic chemistry
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