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Book synopsis

This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.

Book details

Book category Books in English Mathematics & science Chemistry Physical chemistry

• Full title: MWW-Type Titanosilicate
• Subtitle: Synthesis, Structural Modification and Catalytic Applications to Green Oxidations
• Author: Peng Wu, Hao Xu, Le Xu, Yueming Liu
• Language: English
• Binding: Paperback
• Number of pages: 125
• EAN: 9783642391149
• ISBN: 3642391141
• ID: 01663925
• Publisher: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
• Weight: 2175 g
• Dimensions: 235 × 155 × 10 mm
• Date of publishing: 05. August 2013

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