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Book synopsis

This guide is based on the synthesis of bisquinlone based phosphine ligands and desulfitative carbon-carbon bond forming reactions. It is divided into 3 chapters which include first an overview about heterocyclic BINAP analogues. In this chapter, survey of developing atropisomeric biheteroaryl backbone-containing bisphosphines, their designing concept, synthetic approaches and some of their important applications are discussed. Second, efficient synthesis of functionalized novel bisquinolone based mono- and diphosphine ligands of the aza-BINAP type. Preliminary studies confirm that these novel types of aza-BINAP phosphines containing an enamide moiety incorporated into the heteroaryl ring are indeed useful ligands in transition metal-catalyzed transformations. Third, palladium(0)- catalyzed, copper(I)-mediated desulfitative C C cross-coupling protocol (Liebeskind Srogl type) of cyclic thioamides and thioureas with alkenylboronic acids, vinyl- and (het)arylstannanes, and arylsiloxanes is performed. These C C cross-couplings are a valuable extension of the traditional Liebeskind Srogl reactions utilizing thioethers as electrophilic reagents.

Book details

Book category Books in English Mathematics & science Chemistry Organic chemistry

• Full title: C-P and C-C Bond Forming Reactions Based on Carbostyrils and Thioamide
• Subtitle: Phosphine Ligands and Thioamide Derivatives
• Author: Nuzhat Arshad
• Language: English
• Binding: Paperback
• Number of pages: 92
• EAN: 9783639256604
• ISBN: 3639256603
• ID: 06833088
• Publisher: VDM Verlag
• Weight: 145 g
• Dimensions: 229 × 152 × 6 mm
• Date of publishing: 13. May 2010

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